| 1. Round | 13/09/2020 | Liverpool FC U23 | - | Everton FC U23 | 1:0 |  |
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| 2. Round | 18/09/2020 | Derby County U23 | - | Liverpool FC U23 | 2:1 | ||||
| 3. Round | 25/09/2020 | Manchester United U23 | - | Liverpool FC U23 | 3:5 | |
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| 7. Round | 30/10/2020 | Arsenal FC U23 | - | Liverpool FC U23 | 0:1 | ||||
| 9. Round | 21/11/2020 | Liverpool FC U23 | - | Southampton FC U23 | 0:0 | ||||
| 10. Round | 28/11/2020 | Liverpool FC U23 | - | Manchester City U23 | 2:7 | ||||
| 11. Round | 12/12/2020 | Liverpool FC U23 | - | Blackburn Rovers U23 | 1:2 | ||||
| 12. Round | 19/12/2020 | Liverpool FC U23 | - | Tottenham Hotspur U23 | 3:4 | |
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| 19. Round | 19/02/2021 | Chelsea FC U23 | - | Liverpool FC U23 | 2:3 | |
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| 20. Round | 27/02/2021 | Liverpool FC U23 | - | Arsenal FC U23 | 4:0 | ||||
| 15. Round | 07/03/2021 | Liverpool FC U23 | - | Derby County U23 | 1:4 | ||||
| 21. Round | 13/03/2021 | Liverpool FC U23 | - | West Ham United U23 | 1:1 |  |
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| 23. Round | 09/04/2021 | Manchester City U23 | - | Liverpool FC U23 | 3:2 | |
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| 25. Round | 23/04/2021 | Tottenham Hotspur U23 | - | Liverpool FC U23 | 4:1 |
Northern Ireland