| 1. Round | 24/08/2014 | SC Paderborn 07 | - | 1. FSV Mainz 05 | 2:2 | ||||
| 2. Round | 31/08/2014 | 1. FSV Mainz 05 | - | Hannover 96 | 0:0 | ||||
| 3. Round | 13/09/2014 | Hertha BSC | - | 1. FSV Mainz 05 | 1:3 | ||||
| 4. Round | 20/09/2014 | 1. FSV Mainz 05 | - | Borussia Dortmund | 2:0 | ||||
| 6. Round | 26/09/2014 | 1. FSV Mainz 05 | - | 1899 Hoffenheim | 0:0 | ||||
| 7. Round | 05/10/2014 | Bor. Mönchengladbach | - | 1. FSV Mainz 05 | 1:1 | ||||
| 8. Round | 18/10/2014 | 1. FSV Mainz 05 | - | FC Augsburg | 2:1 | ||||
| 32. Round | 09/05/2015 | VfB Stuttgart | - | 1. FSV Mainz 05 | 2:0 | ||||
| 34. Round | 23/05/2015 | Bayern München | - | 1. FSV Mainz 05 | 2:0 |
Germany