1. Round 13/09/1964 UD Las Palmas - FC Barcelona 2:1 Goal
2. Round 20/09/1964 FC Barcelona - Atlético Madrid 2:3 Goal
3. Round 27/09/1964 Deportivo La Coruña - FC Barcelona 1:2 Goal
4. Round 04/10/1964 FC Barcelona - Real Murcia 8:1 GoalGoal
5. Round 11/10/1964 Levante UD - FC Barcelona 5:1
6. Round 18/10/1964 FC Barcelona - Athletic Club 4:0 GoalGoal
7. Round 25/10/1964 Sevilla FC - FC Barcelona 2:1
8. Round 01/11/1964 FC Barcelona - Espanyol Barcelona 1:0
9. Round 08/11/1964 Real Madrid - FC Barcelona 4:1 Goal
10. Round 22/11/1964 FC Barcelona - Córdoba CF 4:1 GoalGoal
11. Round 29/11/1964 Elche CF - FC Barcelona 2:0
12. Round 06/12/1964 FC Barcelona - Real Oviedo 5:0 GoalGoal
13. Round 13/12/1964 Valencia CF - FC Barcelona 2:4 Goal
14. Round 20/12/1964 FC Barcelona - Real Zaragoza 2:0 Goal
15. Round 27/12/1964 Real Betis - FC Barcelona 2:1
16. Round 03/01/1965 FC Barcelona - UD Las Palmas 4:0 Goal
17. Round 10/01/1965 Atlético Madrid - FC Barcelona 3:2 Goal
18. Round 17/01/1965 FC Barcelona - Deportivo La Coruña 2:0 Goal
19. Round 24/01/1965 Real Murcia - FC Barcelona 0:2 Goal
20. Round 31/01/1965 FC Barcelona - Levante UD 4:2 GoalGoal
21. Round 07/02/1965 Athletic Club - FC Barcelona 0:0
22. Round 14/02/1965 FC Barcelona - Sevilla FC 4:3 GoalGoalGoal
23. Round 21/02/1965 Espanyol Barcelona - FC Barcelona 0:0
24. Round 28/02/1965 FC Barcelona - Real Madrid 1:2 Goal
25. Round 07/03/1965 Córdoba CF - FC Barcelona 1:0
26. Round 21/03/1965 FC Barcelona - Elche CF 1:1
27. Round 28/03/1965 Real Oviedo - FC Barcelona 2:0
28. Round 04/04/1965 FC Barcelona - Valencia CF 2:0 GoalGoal
29. Round 11/04/1965 Real Zaragoza - FC Barcelona 2:0
30. Round 18/04/1965 FC Barcelona - Real Betis 0:0