| 1. Round | 16/09/1962 | Athletic Bilbao | - | FC Barcelona | 2:3 |  |
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| 2. Round | 23/09/1962 | FC Barcelona | - | Real Betis | 1:0 | ||||
| 4. Round | 07/10/1962 | FC Barcelona | - | Deportivo La Coruña | 5:2 | ||||
| 5. Round | 14/10/1962 | FC Barcelona | - | CD Málaga | 4:0 | |
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| 6. Round | 21/10/1962 | Elche CF | - | FC Barcelona | 1:1 | ||||
| 10. Round | 18/11/1962 | Sevilla FC | - | FC Barcelona | 1:0 | ||||
| 11. Round | 09/12/1962 | FC Barcelona | - | Atlético Madrid | 0:0 | ||||
| 16. Round | 13/01/1963 | FC Barcelona | - | Athletic Bilbao | 0:0 | ||||
| 19. Round | 03/02/1963 | Deportivo La Coruña | - | FC Barcelona | 1:0 | ||||
| 20. Round | 10/02/1963 | CD Málaga | - | FC Barcelona | 0:7 | |
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| 21. Round | 17/02/1963 | FC Barcelona | - | Elche CF | 4:0 | ||||
| 22. Round | 24/02/1963 | Real Valladolid | - | FC Barcelona | 1:0 | ||||
| 23. Round | 03/03/1963 | FC Barcelona | - | Real Oviedo | 2:1 | |
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| 24. Round | 10/03/1963 | Valencia CF | - | FC Barcelona | 0:3 | ||||
| 25. Round | 17/03/1963 | FC Barcelona | - | Sevilla FC | 0:0 | ||||
| 26. Round | 24/03/1963 | Atlético Madrid | - | FC Barcelona | 4:2 | ||||
| 27. Round | 31/03/1963 | FC Barcelona | - | Real Zaragoza | 0:0 |
Spain