| 23. Round | 29/01/2022 | Clyde FC | - | Alloa Athletic | 2:1 | ||||
| 24. Round | 05/02/2022 | Peterhead FC | - | Alloa Athletic | 0:1 |  |
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| 20. Round | 08/02/2022 | Alloa Athletic | - | Falkirk FC | 0:3 | ||||
| 25. Round | 12/02/2022 | Alloa Athletic | - | East Fife FC | 1:3 | ||||
| 27. Round | 26/02/2022 | Alloa Athletic | - | Cove Rangers | 2:2 | ||||
| 29. Round | 12/03/2022 | Queen's Park FC | - | Alloa Athletic | 1:1 | ||||
| 32. Round | 02/04/2022 | Alloa Athletic | - | Dumbarton FC | 2:3 |  |
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| 36. Round | 30/04/2022 | Alloa Athletic | - | Montrose FC | 4:1 |
England