| 1. Round | 30/08/1985 | Valencia CF | - | Real Valladolid | 2:1 | ||||
| 2. Round | 03/09/1985 | Real Valladolid | - | Espanyol Barcelona | 1:0 | ||||
| 3. Round | 07/09/1985 | Racing Santander | - | Real Valladolid | 1:1 | ||||
| 4. Round | 14/09/1985 | Real Valladolid | - | Real Zaragoza | 1:1 | ||||
| 9. Round | 27/10/1985 | Hércules CF | - | Real Valladolid | 1:0 | ||||
| 10. Round | 02/11/1985 | Real Valladolid | - | FC Barcelona | 2:2 | ||||
| 11. Round | 09/11/1985 | Cádiz CF | - | Real Valladolid | 1:0 | ||||
| 12. Round | 16/11/1985 | Real Valladolid | - | UD Las Palmas | 4:2 | ||||
| 26. Round | 22/02/1986 | Real Valladolid | - | Hércules CF | 3:1 |
Spain