| 3. Round | 02/08/2022 | SL Benfica | - | FC Midtjylland | 4:1 | ||||
| 3. Round | 09/08/2022 | FC Midtjylland | - | SL Benfica | 1:3 | ||||
| Play-offs | 17/08/2022 | Dinamo Kiev | - | SL Benfica | 0:2 | ||||
| Play-offs | 23/08/2022 | SL Benfica | - | Dinamo Kiev | 3:0 |
| 3. Round | 02/08/2022 | SL Benfica | - | FC Midtjylland | 4:1 | ||||
| 3. Round | 09/08/2022 | FC Midtjylland | - | SL Benfica | 1:3 | ||||
| Play-offs | 17/08/2022 | Dinamo Kiev | - | SL Benfica | 0:2 | ||||
| Play-offs | 23/08/2022 | SL Benfica | - | Dinamo Kiev | 3:0 |
| Alejandro Grimaldo García | |
| Born: | 20.09.1995 |
| Place of birth: |
Valencia, 
Spain |
| Nationality: |
Spain
|
| Height: | 171 cm |
| Weight: | 69 kg |
| Position(s): | Left Back Left Midfielder |
| Foot: | left |
