| 3. Round | 04/08/2021 | Spartak Moskva | - | SL Benfica | 0:2 | ||||
| 3. Round | 10/08/2021 | SL Benfica | - | Spartak Moskva | 2:0 | ||||
| Play-offs | 18/08/2021 | SL Benfica | - | PSV Eindhoven | 2:1 | ||||
| Play-offs | 24/08/2021 | PSV Eindhoven | - | SL Benfica | 0:0 |
| 3. Round | 04/08/2021 | Spartak Moskva | - | SL Benfica | 0:2 | ||||
| 3. Round | 10/08/2021 | SL Benfica | - | Spartak Moskva | 2:0 | ||||
| Play-offs | 18/08/2021 | SL Benfica | - | PSV Eindhoven | 2:1 | ||||
| Play-offs | 24/08/2021 | PSV Eindhoven | - | SL Benfica | 0:0 |
| Alejandro Grimaldo García | |
| Born: | 20.09.1995 |
| Place of birth: |
Valencia, 
Spain |
| Nationality: |
Spain
|
| Height: | 171 cm |
| Weight: | 69 kg |
| Position(s): | Left Back Left Midfielder |
| Foot: | left |
