1. Round | 25/08/2012 | SC Freiburg | - | 1. FSV Mainz 05 | 1:1 | ||||
2. Round | 31/08/2012 | 1. FSV Mainz 05 | - | SpVgg Greuther Fürth | 0:1 | ||||
3. Round | 15/09/2012 | Bayern München | - | 1. FSV Mainz 05 | 3:1 | ||||
4. Round | 22/09/2012 | 1. FSV Mainz 05 | - | FC Augsburg | 2:0 | ||||
5. Round | 25/09/2012 | FC Schalke 04 | - | 1. FSV Mainz 05 | 3:0 | ||||
6. Round | 30/09/2012 | VfL Wolfsburg | - | 1. FSV Mainz 05 | 0:2 | ||||
7. Round | 06/10/2012 | 1. FSV Mainz 05 | - | Fortuna Düsseldorf | 1:0 | ||||
34. Round | 18/05/2013 | VfB Stuttgart | - | 1. FSV Mainz 05 | 2:2 |