9. Round | 17/10/2022 | Villarreal CF | - | CA Osasuna | 2:0 | ||||
10. Round | 20/10/2022 | FC Barcelona | - | Villarreal CF | 3:0 | ||||
11. Round | 23/10/2022 | Villarreal CF | - | UD Almería | 2:1 | ||||
14. Round | 09/11/2022 | Espanyol Barcelona | - | Villarreal CF | 0:1 | ||||
17. Round | 13/01/2023 | RC Celta | - | Villarreal CF | 1:1 |