2. Round | 24/08/2019 | 1. FSV Mainz 05 | - | Bor. Mönchengladbach | 1:3 | ||||
3. Round | 31/08/2019 | Bayern München | - | 1. FSV Mainz 05 | 6:1 | ||||
4. Round | 14/09/2019 | 1. FSV Mainz 05 | - | Hertha BSC | 2:1 | ||||
7. Round | 05/10/2019 | SC Paderborn 07 | - | 1. FSV Mainz 05 | 1:2 | ||||
11. Round | 09/11/2019 | 1. FSV Mainz 05 | - | 1. FC Union Berlin | 2:3 | ||||
26. Round | 17/05/2020 | 1. FC Köln | - | 1. FSV Mainz 05 | 2:2 | ||||
32. Round | 17/06/2020 | Borussia Dortmund | - | 1. FSV Mainz 05 | 0:2 | ||||
34. Round | 27/06/2020 | Bayer Leverkusen | - | 1. FSV Mainz 05 | 1:0 |