| #1 | 13/05/1962 | Belgium | - | Italy | 1:3 | ||||
| #2 | 31/05/1962 | Germany | - | Italy | 0:0 | ||||
| #3 | 11/11/1962 | Austria | - | Italy | 1:2 | ||||
| #4 | 02/12/1962 | Italy | - | Turkey | 6:0 |  |
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| #5 | 12/05/1963 | Italy | - | Brazil | 3:0 | ||||
| #6 | 09/06/1963 | Austria | - | Italy | 0:1 | ||||
| #7 | 13/10/1963 | USSR | - | Italy | 2:0 | ||||
| #8 | 10/11/1963 | Italy | - | USSR | 1:1 | |
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| #9 | 14/12/1963 | Italy | - | Austria | 1:0 | |
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| #10 | 11/04/1964 | Italy | - | CSSR | 0:0 | ||||
| #11 | 10/05/1964 | Switzerland | - | Italy | 1:3 | |
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| #12 | 04/11/1964 | Italy | - | Finland | 6:1 | |
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| #13 | 05/12/1964 | Italy | - | Denmark | 3:1 | ||||
| #14 | 13/03/1965 | Germany | - | Italy | 1:1 | ||||
| #15 | 18/04/1965 | Poland | - | Italy | 0:0 | ||||
| #16 | 27/06/1965 | Hungary | - | Italy | 2:1 | ||||
| #17 | 01/11/1965 | Italy | - | Poland | 6:1 | |
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| #18 | 09/11/1965 | Scotland | - | Italy | 1:0 | ||||
| #19 | 07/12/1965 | Italy | - | Scotland | 3:0 | ||||
| #20 | 19/03/1966 | France | - | Italy | 0:0 | ||||
| #21 | 14/06/1966 | Italy | - | Bulgaria | 6:1 | ||||
| #22 | 22/06/1966 | Italy | - | Argentina | 3:0 | ||||
| #23 | 29/06/1966 | Italy | - | Mexico | 5:0 | |
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| #24 | 13/07/1966 | Italy | - | Chile | 2:0 | ||||
| #25 | 19/07/1966 | North Korea | - | Italy | 1:0 | ||||
| #26 | 22/03/1967 | Cyprus | - | Italy | 0:2 | ||||
| #27 | 27/03/1967 | Italy | - | Portugal | 1:1 | ||||
| #28 | 25/06/1967 | Romania | - | Italy | 0:1 | ||||
| #29 | 23/12/1967 | Italy | - | Switzerland | 4:0 | ||||
| #30 | 06/04/1968 | Bulgaria | - | Italy | 3:2 | ||||
| #31 | 20/04/1968 | Italy | - | Bulgaria | 2:0 | ||||
| #32 | 05/06/1968 | Italy | - | USSR | 0:0 aet | ||||
| #33 | 23/10/1968 | Wales | - | Italy | 0:1 | ||||
| #34 | 01/01/1969 | Mexico | - | Italy | 2:3 | ||||
| #35 | 29/03/1969 | GDR | - | Italy | 2:2 | ||||
| #36 | 04/11/1969 | Italy | - | Wales | 4:1 | ||||
| #37 | 21/02/1970 | Spain | - | Italy | 2:2 | ||||
| #38 | 10/05/1970 | Portugal | - | Italy | 1:2 | ||||
| #39 | 11/06/1970 | Italy | - | Israel | 0:0 | ||||
| #40 | 14/06/1970 | Italy | - | Mexico | 4:1 | |
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| #41 | 17/06/1970 | Italy | - | Germany | 4:3 aet | |
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| #42 | 21/06/1970 | Brazil | - | Italy | 4:1 | ||||
| #43 | 31/10/1970 | Austria | - | Italy | 1:2 | ||||
| #44 | 20/02/1971 | Italy | - | Spain | 1:2 | ||||
| #45 | 25/09/1971 | Italy | - | Mexico | 2:0 | ||||
| #46 | 09/10/1971 | Italy | - | Sweden | 3:0 | ||||
| #47 | 20/09/1972 | Italy | - | Yugoslavia | 3:1 | ||||
| #48 | 07/10/1972 | Luxembourg | - | Italy | 0:4 | ||||
| #49 | 21/10/1972 | Switzerland | - | Italy | 0:0 | ||||
| #50 | 12/01/1973 | Italy | - | Turkey | 0:0 | ||||
| #51 | 31/03/1973 | Italy | - | Luxembourg | 5:0 | |
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| #52 | 09/06/1973 | Italy | - | Brazil | 2:0 | ||||
| #53 | 14/06/1973 | Italy | - | England | 2:0 | ||||
| #54 | 29/09/1973 | Italy | - | Sweden | 2:0 | ||||
| #55 | 20/10/1973 | Italy | - | Switzerland | 2:0 | |
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| #56 | 13/11/1973 | England | - | Italy | 0:1 | ||||
| #57 | 25/02/1974 | Italy | - | Germany | 0:0 | ||||
| #58 | 08/06/1974 | Austria | - | Italy | 0:0 | ||||
| #59 | 15/06/1974 | Italy | - | Haiti | 3:1 | |
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| #60 | 19/06/1974 | Argentina | - | Italy | 1:1 |
Italy