16. Round | 21/01/2023 | VfB Stuttgart | - | 1. FSV Mainz 05 | 1:1 | ||||
17. Round | 25/01/2023 | 1. FSV Mainz 05 | - | Borussia Dortmund | 1:2 | ||||
18. Round | 28/01/2023 | 1. FSV Mainz 05 | - | VfL Bochum | 5:2 | ||||
19. Round | 04/02/2023 | 1. FC Union Berlin | - | 1. FSV Mainz 05 | 2:1 | ||||
20. Round | 11/02/2023 | 1. FSV Mainz 05 | - | FC Augsburg | 3:1 | ||||
21. Round | 19/02/2023 | Bayer Leverkusen | - | 1. FSV Mainz 05 | 2:3 | ||||
33. Round | 21/05/2023 | 1. FSV Mainz 05 | - | VfB Stuttgart | 1:4 | ||||
34. Round | 27/05/2023 | Borussia Dortmund | - | 1. FSV Mainz 05 | 2:2 |